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So Witcher is amazing... I like it better than Elder Scrolls... question, I'm not big into potions and such... whenever I've delved into them I always feel like it was needless... what am I missing.
You have to put 8 points into the first tier of the Alchemy tree (3 points into Acquired Tolerance 5 points into and Heightened Tolerance) to raise your max toxicity high enough to run multiple decoctions at once. Then you keep Ekimmara, Ekhidna, and Water Hag up at all times. Huge boost to damage and survivability. Add on the Euphoria mutation from Blood and Wine and enemies simply explode upon first contact.
After that, Tawny Owl is the most useful combat potion. Thunderbolt and Maribor Forest are good for topping off damage if you've got the spare toxicity (but I usually don't). Use utility potions like Cat or Killer Whale as needed.
side- I play on various difficulties but usually roll on Story and Swords... I've kicked it up and down at various times.
The proper difficulty really depends on how much you've optimized your build and gear. I did Blood and Broken Bones on my first playthrough, and am currently on Death March for New Game +.
